Nylon Tubing

Nylon tubing, also known as polyamide tubing, is a type of tubing made from polyamide resin, which has a strong resistance to abrasion. It is used in high-pressure and high-temperature applications...

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This article will take an in-depth look at Polyvinyl Chloride (PVC)
The article will take a look at topics such as:
This part dives into Polyvinyl Chloride (PVC), elucidating the procedure used in its manufacturing.
Polyvinyl Chloride, abbreviated as PVC, is a robust, white, brittle thermoplastic known for being lightweight yet resilient. Economically feasible and easy to process, PVC was originally synthesized by German chemist Eugen Baumann in 1872. He discovered it by exposing a tube filled with vinyl chloride gas to sunlight, resulting in the formation of a white solid, which we call PVC today. Widespread use only began in 1913, primarily as a corrosion-resistant piping material.
PVC is available in several variants, such as flexible, unplasticized, perchlorovinyl, molecularly oriented, and modified forms. Its hallmark properties include dielectric strength, durability, flame retardancy, low cost, and resistance to abrasion and chemicals.
Given that PVC resin generated by polymerization displays low thermal stability and high melt viscosity, its attributes are often modified using various additives in production. Additives like heat stabilizers, UV protectants, plasticizers, impact modifiers, fillers, flame retardants, and pigments enhance PVC's stability.
PVC is created by polymerizing vinyl chloride, with its features changing based on the plasticizer applied. Plasticizers are low molecular weight substances added to increase PVC's flexibility and plasticity. They primarily adjust the polymer's attributes to fit specific applications. For optimal performance, plasticizers should have chemical compatibility with the PVC polymer.
This section delves into how Polyvinyl Chloride is manufactured.
Unlike other thermoplastics fully reliant on petroleum, PVC is made from two key raw materials, reducing dependence on non-renewable fossil fuels during production. Specifically, 57% of PVC comes from common salt, while the remaining 43% derives from hydrocarbon feedstocks.
Recently, ethylene from sugar crops has been increasingly used as an alternative to natural gas or oil-derived ethylene for PVC production. Though PVC is commonly made from oil and salt, in certain regions it is produced without any oil feedstock, substituting oil-derived hydrocarbons with bio-sourced ones, making it less dependent on oil compared to other thermoplastics.
Known for exceptional durability and energy efficiency, PVC is apt for varied applications. Raw materials for PVC are abundant, with plentiful salt reserves found both in the sea and underground.
The PVC manufacturing process involves five stages:
Ethylene, derived from natural gas, is provided by the petrochemical sector. Extracting ethylene involves a cracking process, where liquid petroleum is heated in furnaces with steam under high pressure. This alters the molecular composition of the petroleum feedstocks, allowing ethylene to be identified, separated, and collected, before being cooled to a liquefied state.
Chlorine is obtained from seawater or salt using electrolysis, adding an extra electron. A powerful electric current passed through a saltwater solution changes its molecular structure, separating the chlorine. When chlorine reacts with ethylene, ethylene dichloride (EDC) is formed. EDC undergoes thermal cracking to yield vinyl chloride monomer (VCM).
VCM enters a reactor with a catalyst to start polymerization, the phase binding vinyl chloride monomers into PVC resin, which forms the base for several vinyl products. PVC naturally appears translucent and is resistant to both chemicals and fire.
To yield vinyl compounds with distinct properties, PVC is combined with various plasticizers, stabilizers, and modifiers. These additives amplify attributes like UV resilience, color retention, abrasion resistance, weatherability, and texture capabilities.
This section outlines the emulsion polymerization technique employed in creating PVC.
In this process, monomer droplets are suspended in water, acting as individual reactors. Aided by an organic catalyst, polymerization begins in a small bulk form. As polymerization progresses, droplets change into sticky, viscous particles.
The particles eventually solidify into spherical polymers through vigorous stirring and steric stabilizers. These particles are typically several hundred micrometers in size. Suspension polymerization effectively produces polymers from highly reactive monomers via radical polymerization.
Water aids in the process's agitation and heat transfer. The conversion of monomers keeps the suspension's viscosity relatively steady. Isolated polymer particles are separated from water for further applications. In suspension polymerization, the final polymer particle size distribution (PSD) reflects the monomer droplet size distribution, with minimal shrinkage and mass transfer among particles.
Steric stabilizer type and quantity influence the PSD, which stirring and vessel design also affect. A stable suspension is maintained through controlled agitation and varied stabilizers to achieve desired density, size, and porosity. Two suspension polymerization types exist, including nonporous beads formed when the polymer dissolves in monomers, like PMMA and PS.
Conversely, powders arise when the polymer does not dissolve in the monomer and forms numerous primary particles, presenting opacity and high internal porosity. Porosity control is essential as it influences plasticizer absorption rates, such as with PVC.
Within this method, both monomer solution and initiator are continuously fed into the reactor. Monomer feed, as an oil phase, can be pre-emulsified in water with surfactants, forming an emulsion. Emulsification can occur in a separate or inline vessel using static mixers, ultrasonic devices, or high-pressure systems.
Utilizing a monomer emulsion feed enhances temperature control and process safety while reducing reactor fouling. Achieving over 95% conversion means copolymerization parameters become less critical. Instead, polymer properties align closely with the ratio of monomers fed. Introducing monomers this way allows precise control over particle composition and form by adjusting separate monomer feed rates. A particle seed often regulates number and final size.
Adding another set of particles introduces either additional seed or sufficiently concentrated surfactant to form micelles, creating a bimodal particle size distribution. This approach achieves high solids content with lower viscosity. Multimodal size distributions may also form via agglomeration agents during emulsion processing.
Incremental cross-linking monomer additions adjust particle morphology. Industrial reactor design and hydrodynamic flow conditions are vital for maintaining stability and efficient heat transfer, with factors like stirrer type and reactor design being significant.
Often labeled mass polymerization, this method foregoes a solvent, using only an initiator and monomer. As polymerization progresses, the polymer molds to the vessel's interior. Managing the heat generated during this process remains a primary challenge.
This straightforward approach suits cast-molded items, including polystyrene scintillators. Data suggests distilling the monomer before initiating the reaction to boost polymerization rate. If distillation isn't viable, a suitable solution rinse is advised.
Bulk polymerization's formulation simplicity stems from the exclusion of solvents or dispersants, making it apt for various chain-growth and step-growth polymers. However, exothermic chain-growth reactions can become overly vigorous and challenging without efficient cooling systems in the reactor.
Moreover, bulk polymerizations often present stirring challenges due to the viscosity of high-molecular-weight polymers formed.
In the United States and Canada, there are many machines designed for the production of PVC tubing. These machines are crucial in modern industry because they facilitate the efficient and economical manufacturing of PVC tubing, which is essential for a wide range of applications including construction, electronics, and automotive sectors. The following sections will explore some of the leading machines used in this field.
Features: The Conical Twin Screw Extruder is a popular choice for PVC tubing manufacturing because it efficiently processes PVC compounds, delivers high production rates, and provides superior melt uniformity, ensuring consistent quality in the tubing.
Features: The Single Screw Extruder is favored for PVC tubing production due to its versatility, affordability, and capability to efficiently process a range of PVC formulations.
Features: Davis-Standard provides a variety of downstream equipment tailored for PVC tubing production, such as vacuum sizing tanks, haul-off units, and cutting systems. These tools ensure precise dimensions and a smooth surface finish for the tubing.
Features: Bausano Twin Screw Extruders are renowned in PVC tubing manufacturing for their advanced design, precise control, and high production capacity. They efficiently handle a range of PVC formulations and deliver consistent quality in the tubing.
Manufacturer: American Kuhne (a division of Graham Engineering Corporation)
Features: American Kuhne provides a range of extrusion equipment for PVC tubing production, including extruders, crossheads, and downstream systems, all noted for their precision and dependability.
Note: The details provided reflect information available as of the article's posting date. Newer models or manufacturers may have emerged since then. For the latest information, it is advisable to consult industry-specific sources or contact manufacturers, suppliers, and experts directly.
This section will cover the different types of PVC pipes, their characteristics, and the additives used in PVC formulations.
The different types of PVC pipes include:
If a pipe is labeled with an additional 'U' at the end, it indicates that the pipe is made from unplasticized PVC (PVC-U). This type of PVC lacks plasticizers—substances added to PVC to increase its plasticity and flexibility and reduce brittleness. As a result, PVC-U is commonly referred to as rigid PVC.
Unplasticized PVC (PVC-U) is the most widely used type of PVC for pipes and fittings. It is commonly employed for transporting both drinking water and wastewater. These pipes are valued for their ease of handling, lightweight nature, affordability, and durability. Additionally, the absence of plasticizers makes them fully recyclable.
PVC-O is a type of PVC that has been molecularly oriented. During its production process, PVC-U is transformed into a layered structure, enhancing its resistance to corrosion.
PVC-O combines stiffness, strength, and flexibility effectively. Its high hydraulic capacity and durability make it ideal for pressure pipes used in irrigation, drinking water systems, and sewer pumping mains.
C-PVC, or chlorinated PVC, shares similar characteristics with PVC-U. It is specifically designed for transporting drinking water and is known for its outstanding corrosion resistance.
The chlorination process used for C-PVC enables it to endure a wider temperature range compared to other types of PVC. As a result, C-PVC is commonly employed in both residential and commercial construction applications.
PVC-Hi, or Hi Impact PVC pipes, are traditional PVC pipes enhanced with modifiers to significantly increase their resistance to external impacts. Their composition includes a blend of compounds with PVC to improve durability. These pipes are designed to perform effectively under high pressure and maintain long-term strength.
To be classified as PVC-Hi, a pipe must adhere to numerous standards and regulations. It must meet stringent requirements due to its use in transporting natural gas, a highly volatile substance.
PVC cables are known for their durability, thin profile, and eco-friendliness. They are engineered to endure extreme weather conditions and are fire-resistant. With a lifespan exceeding twenty years, these cables are commonly used in construction projects. Their slender diameter allows for easy installation in indoor wiring systems, as more wires can be accommodated within a conduit.
The robust construction of PVC cables ensures they are resistant to weather, chemicals, and aging, making them a reliable choice. Their versatility and flexibility make PVC cables adaptable to various applications.
PVC cables are electrical wires with PVC insulation. This material is favored for its resilience under diverse conditions, making it suitable for a range of uses including domestic appliance wiring, internal circuits, and home wiring. The flexibility of PVC cables means there is a type available for every application, so selecting the appropriate cable for the specific conditions is crucial.
PVC siding is a type of protective cladding used for homes and window frames. Like other PVC products, it is durable, cost-effective, and contributes to energy conservation through its excellent airtight insulation and sealing properties. PVC siding addresses the issues commonly associated with wood siding, becoming a standard choice for home protection. It does not require repainting and can be easily cleaned with soap and water or other cleaners.
The popularity of PVC siding stems from its seamless, finished appearance. Each panel interlocks to create a tight, secure seal. PVC siding outlasts wood, requiring no maintenance and maintaining a pristine look without fading, cracking, or peeling.
PVC packaging offers flexibility, lightweight properties, and cost-effectiveness. It is transparent, durable, and safe, with no impact on the taste of the contents. Its tight seal guards against contaminants, dirt, dust, and microorganisms. Additionally, PVC’s resistance to water and oxygen helps prevent food spoilage, extending the shelf life of products.
One of the provisions of the medical field is the immediate disposal of medical equipment and devices such as syringes, gloves, and anything that comes in contact with the patient. PVC packaging is used to collect medical devices for radiation sterilization. As an additional safety measure, blister packages for pills and capsules are made of PVC to ensure that they have not been tampered with.
PVC is used in a wide range of home products, including protective clothing, shower curtains, tents, flooring, and tarps, among others. Its versatility and adaptability make it an excellent choice for numerous applications. PVC's stability and durability ensure that products remain functional for many years with minimal wear.
The applications of PVC in the household are virtually limitless. Through various plastic manufacturing processes, engineers create items such as chairs, bowls, trash cans, mixing bowls, and high chairs using PVC as the primary material. It is one of the most common and widely utilized plastic products available today.
The examples of PVC products provided here represent just a fraction of the many items made from this versatile and essential material. Thanks to its remarkable strength and reliability, new PVC products are continuously being developed and introduced.
Clear PVC is valuable for monitoring system operations in real-time, making it essential for laboratories, product manufacturing, and production environments. It is particularly important in clean room settings, where continuous visibility of processes is crucial for maintaining the room’s integrity.
Like other forms of PVC, clear PVC is resistant to corrosion, enabling it to withstand acids, bases, and other corrosive substances. Its smooth interior surfaces facilitate the unobstructed flow of materials, preventing sediment buildup. Clear PVC is also well-suited for medical and sterile environments due to its resistance to bacterial and biological growth.
Standard PVC is a transparent, amorphous thermoplastic, while CPVC (Chlorinated Polyvinyl Chloride) offers excellent mechanical strength and impact resistance with clear visibility. CPVC is also formulated to resist UV radiation, making it suitable for exterior applications.
Clear PVC is produced through the chlorination of PVC polymer, increasing the chlorine content to 66%. This process reduces the attraction between molecular chains, making the material more flexible and easier to stretch. In CPVC, about 40% of the bonding sites are occupied by chlorine atoms, which are large and provide protection to the polymer chain.
Batching is a crucial step in manufacturing clear PVC. It involves precisely formulating the PVC resin along with plasticizers, stabilizers, and other additives. Accurate measurement and control of these components are essential, as any deviations can adversely affect the final product. The batching process results in pellets or powder, which are then used for further processing.
Chlorination modifies the properties of PVC to produce clear PVC. This involves exposing the PVC material to a controlled amount of chlorine gas. For clear PVC, chlorination improves its resistance to high temperatures and chemicals. During this process, chlorine gas reacts with the PVC, integrating chlorine atoms into the polymer chain.
In the extrusion process, the powder or pellets from chlorination are fed into an extruder's hopper. As these materials are moved through the extruder barrel by a screw, they are heated and melted before being forced through a die under pressure. This process is used to create clear profiles and tubing.
Calendaring is used to produce sheets of clear PVC. The PVC powder is heated until it becomes soft and pliable. It is then passed through rollers that compress, flatten, and shape the material into sheets of various thicknesses, ranging from a fraction of an inch to several inches.
Clear PVC's strength and durability extend its applications beyond medical and research uses. The increased strength provided by the chlorination process makes clear PVC suitable for a range of industrial applications, demonstrating its versatility and importance in various fields.
Clear PVC's popularity has surged as its applications continue to expand. Its unique properties and characteristics make it an excellent alternative to metal in critical applications. Its versatility, combined with its strength and durability, makes it a preferred material for various demanding uses.
Clear PVC’s physical properties, characteristics, and specifications make it an ideal choice for applications in chemical processing, mineral processing, and handling hazardous materials. Its durability and reliability ensure effective performance in harsh and demanding industrial environments.
PVC is produced in two primary forms: rigid or unplasticized PVC (RPVC or uPVC) and flexible plasticized PVC. In its natural state, PVC is rigid and brittle, requiring enhancement through various additives and stabilizers to improve its properties.
Rigid PVC is commonly used in applications such as sewage disposal, agriculture, and plumbing due to its strength and durability. In contrast, plasticized PVC is made more flexible and softer by adding plasticizers like phthalates (e.g., diisononyl phthalate or DINP). This flexibility makes plasticized PVC suitable for uses such as electrical wire insulation and flooring in hospitals, schools, and other environments where sterility is important. It is sometimes used as an alternative to rubber. Unplasticized PVC is frequently employed in construction, particularly for plumbing pipes and siding.
Rigid PVC does not include phthalates, which are chemicals used to enhance flexibility in PVC products. When PVC lacks phthalates, it is referred to as uPVC or rigid PVC. This type of PVC is often used for water containers and building materials, and it is known for its fade resistance, with color extending throughout its thickness.
uPVC has a broad range of applications and is commonly used as a construction material and as a replacement for copper and aluminum piping in waste systems, irrigation, and pool circulation. Its ease of forming and cutting makes it a practical alternative to metal products.
PVC and CPVC differ significantly in their temperature tolerance. CPVC can withstand temperatures up to 200 degrees Fahrenheit, whereas PVC is suitable for temperatures up to 140 degrees Fahrenheit.
Exceeding these temperature limits causes both PVC and CPVC to soften, increasing the risk of joint failure and compromising the integrity of the plumbing system. Additionally, due to their distinct chemical compositions, the bonding agents, solvent cements, and primers used for CPVC and PVC are not interchangeable.
PVC is known for its high density relative to most other plastics, making it both readily available and cost-effective. Unplasticized rigid PVC is particularly noted for its hardness and durability, and it offers excellent tensile strength. As a thermoplastic, PVC behaves similarly to other plastics when exposed to heat: it melts and becomes a liquid at its melting point.
PVC has a range of melting points from 100 degrees Celsius to higher values like 260 degrees Celsius depending on the types of additives. Thermoplastics can be heated until they reach their melting point, cooled, and reheated again without any significant degradation. Instead of burning, thermoplastics such as propylene liquefy allows them to be injection molded in an easy way and then recycled subsequently.
In contrast, thermosetting plastics can only be heated once, typically during the injection molding process. During this initial heating, thermosets undergo a chemical change that sets their structure irreversibly. If a thermoset material is reheated, it simply burns rather than melting. This property limits the recyclability of thermoset materials.
The fundamental chemical structure of PVC is outlined below.
PVC, or polyvinyl chloride, has the chemical formula (C2H3Cl)n. It contains more than 50% chlorine by weight.
Various additives used in PVC include:
Lubricants are utilized for the reduction of friction during processing. External lubricants can reduce friction between the polymer and the equipment for processing, whereas internal lubricants work on the granules of the polymer (PVC).
Flexible PVC applications, such as extruded profiles, injection-molded soles, and calendered films, commonly use liquid mixed metal stabilizers. These stabilizers are primarily composed of zinc, barium, and carboxylates.
For optimal performance, co-stabilizers, antioxidants, and organophosphates are often required in liquid mixed metal systems like CaZn and BaZn. Cadmium-based stabilizers have largely been replaced by BaZn stabilizers due to their effectiveness and environmental benefits.
Heat stabilizers are crucial in PVC formulations to prevent decomposition caused by heat and shear during processing. They also enhance PVC's resistance to sunlight, thermal aging, and weathering. Additionally, heat stabilizers significantly impact the physical properties and cost of the PVC formulation. The selection of a heat stabilizer depends on several factors, including the technical specifications of the polymer product, cost considerations, and regulatory compliance.
A plasticizer is an additive used in polymers to enhance flexibility, resilience, and workability. The selection of plasticizers is guided by the desired properties of the final product and its intended application. There are over 300 different plasticizers available, with approximately 50 to 100 commonly used in commercial applications. Phthalates are among the most frequently used plasticizers, and they can be categorized into distinct groups based on their specific uses and chemical classes.
Low molecular weight phthalates, which contain eight or fewer carbon atoms in their chemical structure, include DBP, BBP, DIBP, and DEHP. These phthalates are typically used in a limited range of specific applications due to their properties and regulatory considerations.
High molecular weight phthalates, which contain 7 to 13 carbon atoms in their chemical structure, include DPHP, DTDP, DIUP, DIDP, and DINP. These phthalates are commonly used in various applications, such as cables and flooring, where they provide durability and flexibility.
Specialty plasticizers, such as adipates, benzoates, citrates, and trimellitates, are employed when specific physical properties are required. These may include enhanced flexibility at low temperatures or other unique characteristics tailored to particular applications.
Many of the PVC products that are used everyday but tend to be taken for granted consist of phthalate plasticizers. They include blood bags, electrical cables, footwear, stationery, toys, and medical tubing. Phthalates are utilized in other non-PVC applications like rubber products, paints, adhesives, and some cosmetics.
While not essential for maintaining the plastic's structural integrity, optional additives are used to impart additional properties. These include impact modifiers, processing aids, nitrile rubbers, filters, flame retardants, pigments, and colorants.
This chapter will explore the benefits of PVC, including its various applications and the processes involved in recycling it.
Despite its many advantages, PVC also has some drawbacks, including:
Despite its drawbacks, the advantages of PVC are significant and numerous. Here’s a closer look at its benefits:
PVC excels in electrical insulation, making it a top choice for cabling applications. It is also known for its strong impact resistance and weather durability, which make it ideal for construction materials. Additionally, PVC is widely approved for use in medical and food contact applications due to its safety and reliability.
Processing PVC is efficient and requires less energy compared to many other plastics. The material is lightweight yet durable, contributing to its long lifespan.
Another key advantage of PVC is its clarity and neutral taste properties, which make it a preferred material for packaging, as it does not alter the flavor of food products.
Furthermore, PVC has a relatively low carbon footprint. For example, PVC windows can contribute to lower energy bills. The material is fully recyclable and can be easily repurposed into new products, supporting sustainable practices.
PVC pipes offer numerous advantages, including exceptional durability and cost-effectiveness. These benefits make them a highly favorable choice. Below are additional advantages of using PVC pipes:
PVC pipes are highly effective for transporting drinking water due to their resistance to corrosion, which inhibits bacterial growth. This property makes PVC an excellent barrier against contaminants, ensuring safer drinking water for the public.
PVC is a low-carbon plastic, which means it requires fewer resources and less energy to produce compared to other materials. Its lightweight nature simplifies packaging and shipping, and its smooth surface reduces pumping costs, further lowering energy consumption. Additionally, PVC is both recyclable and sustainable.
PVC can be recycled up to seven times while maintaining its properties. Recycling PVC helps conserve natural resources and reduces carbon dioxide emissions, with each kilogram of recycled PVC saving approximately two kilograms of CO2. This makes PVC a highly eco-friendly material, contributing to environmental protection and reducing landfill waste.
Modern industries benefit from PVC's durability and low maintenance requirements. PVC pipes are lightweight yet robust, with a lifespan extending for decades under various conditions. This durability, coupled with lower installation and operating costs, makes PVC a cost-effective choice that requires minimal upkeep.
PVC is widely used in various applications, including:
PVC is utilized in a range of construction applications due to its strength, durability, and versatility. It is particularly well-suited for window profiles and cabling, thanks to its excellent insulation and flame-retardant properties.
Examples of PVC construction products include:
PVC plays a crucial role in numerous life-saving and healthcare applications. Its cost efficiency and exceptional performance make it ideal for use in surgical instruments, drug delivery systems, pharmaceuticals, and medical packaging. PVC’s reliability and versatility contribute significantly to advancements in medical care and treatment.
Examples of PVC healthcare products include:
PVC is widely used as insulation for cables because it is easy to handle during installation, offers flexibility, and has inherent flame retardant properties. PVC cables are known for their strength and longevity, resisting hardening and cracking over time. These characteristics make PVC cables ideal for various applications, including telecommunications and electric blankets.
Here are some common automotive applications for PVC:
PVC's environmental benefits and versatility make it a popular choice in construction, particularly for sporting venues. It is used extensively in roofing, seating, flooring, and electrical wiring and piping. Additionally, PVC is found in various athletic gear, from shoes and clothing to equipment and competition surfaces.
The inherent structure and composition of PVC facilitate its mechanical recycling, allowing for the production of high-quality recycled materials. Proper sorting of PVC is crucial during recycling. The PVC industry has heavily invested in developing advanced recycling technologies to ensure that significant quantities of PVC are repurposed into new, innovative products that are energy-efficient and sustainable.
This investment has enabled the recycling of not only production off-cuts but also end-of-life products such as PVC-U windows and doors on a large global scale. Recycling old windows is more complex than recycling off-cuts due to the need to remove contaminants like building debris before re-processing.
Polyvinyl chloride (PVC) is a tough synthetic polymer that exists in two forms which are plasticized and unplasticized PVC. Plasticized PVC has more plasticity, flexibility, and it’s softer due to the presence of a plasticizer. Many types of plasticizers are available that result in the polymer (PVC) having a variety of properties when added to it. Different PVC products are available with different properties depending on the type of PVC used. It is important to take note of the properties of the type of PVC used in the product that one can purchase for a certain application. To add on, PVC is a material that is long lasting, cheap and it can be applied with greater ease, for example in the electrical field where it is used as insulation for cables. PVC has a great diversity of applications, including floor and wall covering, making doors and windows, sewer pipes, water transport pipes, and natural gas transport pipes.
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